Having a good workflow from camera to web is key. It should be noted that this workflow not a wedding workflow or a image heavy workflow and is one of the more expensive setups. I guess you could call this a premium workflow or a high end workflow. It is designed for photographers who are all about quality over quantity. If you are putting out 8-10 high end images per shoot, have paying clients, you have busy sets and pressure deadlines, this might be the set up for you.
Capture One (Capture) > Capture One (Develop) > Photoshop > Lightroom > SmugMug > WordPress
The interesting here is that each step is using the best program or tool.